Here are few:
open(pathname,flag,mode) - open file
creat(pathname,mode) - create file
close(filedes) - close an open file
read(filedes,buffer,bytes) - read data from an open file
write(filedes,buffer,bytes) - write data to an open file
lseek(filedes,offset,from) - position an open file
dup(filedes) - duplicate an existing file descriptor
dup2(oldfd,newfd) - duplicate to a desired file descriptor
fcntl(filedes,cmd,arg) - change properties of an open file
ioctl(filedes,request,arg) - change the behaviour of an open file
But this may not be complete list...
