RLC_AMD_PDU is just a PDU generated in the RLC_AM mode by the process of segentation and concatination(Based on the availability of resource or TBS value provided by MAC), whereas RLC_AMD_PDU_Segment is the Retransmitting PDU which is being segmented due to the change of TBS value.
Ex: If the PDU with SN = 4 and with the TBS value = 100 is sent and due to some radio link issues it has failed to reach its peer RLC , Now the peer RLC will send the NACK_SN = 4. Obviously, the transmitter RLC entity has to retransmit this PDU, But, if the TBS value is reduced than it was before, lets say 50, Now the Tx RLC has to send 2 PDUs of same SN(4) each of 50 bytes -> "and these PDUs are called RLC AMD PDU segments".
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