For iO6 and below models, you cannot do this.
As of iOS 7, you can find this out using the
currentRadioAccessTechnology property ofCTTelephonyNetworkInfo in the CoreTelephony framework.
#import <CoreTelephony/CTTelephonyNetworkInfo.h>
CTTelephonyNetworkInfo *networkInfo = [CTTelephonyNetworkInfo new];
if ([networkInfo.currentRadioAccessTechnology
isEqualToString:CTRadioAccessTechnologyLTE]) {
// ... }