As per my knowledge of LTE, Once a UE gets attached to LTE network, PGW doesn't change until the UE de-register from network. When UE requests to network to connect new APN and PGW selection is dynamic, in that case MME notifies to HSS about PGW id by using "Notify Request" message over S6a interface.
Notify Request message has "PDN GW Identity field" which tells to HSS about PGW Identity.