You can refer to 29.212 3gpp spec for Gx interface.
In the initial CCR message pgw conveys the information it received from sgw towards pcrf like IMSI, msisdn, APN, bearer control mode, default bearer QoS, IP address of ue(pgw provides it, one of its functionality)
Try reading it and post if you come across any specific doubts.
The AVP used to convey APN into is Called-Station-Id
As per my understanding there is no such AVP to define if call is emergency or not. In case of emergency call an APN based policy should be defined.
Let's say the call comes to pcrf and in CCR initial the called-station-id is emergency.T-Mobile.mcc310.mnc310.GPRS then allow some particular service related to emergency.
I hope that it helped
Regards,
Peeyush Sharma